The Stereochemistry of Organometallic Compounds. XXXV. Hydroformylation of ortho-Propenylanilines and ortho-Propenylphenols: a New Route to 4,5-Dihydro-3H-1-benzazepines
- 1 January 1992
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 45 (1)
- https://doi.org/10.1071/ch9920021
Abstract
Rhodium- catalysed hydroformylation of readily available ortho-propenylanilines gives 4,5- dihydro-3H-1-benzazepines together with small amounts of substituted 3-methylquinolines (≤15%). The regioselectivity of these reactions and the hydroformylation of related ortho-propenylphenols are discussed.Keywords
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