Synthesis and characterisation of iridium carbonyl fluorides
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 18,p. 2945-2948
- https://doi.org/10.1039/dt9950002945
Abstract
Tetrairidium dodecacarbonyl reacted with XeF2 in anhydrous HF solution at low temperatures via sequential fluorination yielding initially fac- and mer-[IrF3(CO)3] and finally IrF5. The novel 18-electron iridium carbonyl fluorides have been characterised by a combination of IR spectroscopy, 13C, 13C-{19F} and 19F NMR spectroscopies and extended X-ray absorption fine structure spectroscopy studies in HF solution.Keywords
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