X-Ray evidence for a mononuclear s-trans-η4-1,3-diene complex; molecular structure of Zr(η5-C5H5)2(s-trans-PhCHCH–CHCHPh)

Abstract
Novel s-trans-η4-co-ordination of butadiene to a single metal atom was Confirmed by the X-ray crystal structure analysis of thermally stable Zr(η5-C5H5)2(PhCHCH–CHCHPh); this agrees with the solution structure determined by 1H n.m.r. spectroscopy.

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