Efficient Synthesis of Cyclopentenones from Enynyl Acetates via Tandem Au(I)-Catalyzed 3,3-Rearrangement and the Nazarov Reaction
Top Cited Papers
- 13 January 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (5) , 1442-1443
- https://doi.org/10.1021/ja057327q
Abstract
A highly efficient method for the synthesis of versatile cyclopentenones from readily available enynyl acetates via tandem Au(I)-catalyzed 3,3-rearrangement and the Nazarov reaction is developed. Significant substrate flexibility and excellent control of the double bond position in the cyclopentenone ring render this an attractive method for cyclopentenone synthesis.Keywords
This publication has 1 reference indexed in Scilit:
- 1,2-Halogen Migration in Haloallenyl Ketones: Regiodivergent Synthesis of HalofuransJournal of the American Chemical Society, 2005