Photochemical Generation of μ-Amido-μ-peroxo-bis[bis(ethylenediamine)cobalt(III)] Complex from the Corresponding μ-Hyperoxo Complex in Neutral Aqueous Solution
- 1 September 1988
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 61 (9) , 3338-3340
- https://doi.org/10.1246/bcsj.61.3338
Abstract
A μ-amido-μ-hyperoxo complex, [(en)2Co(NH2,O2−)Co(en)2]4+, was found to generate the corresponding μ-peroxo complex, together with mononuclear cobalt(III) complexes upon irradiation with near-ultraviolet light in a neutral aqueous solution. The result is different from that obtained in an acidic aqueous solution, in which the products are [Co(NH3)(en)2(H2O)]3+ and Coaq2+. The photochemical reaction mechanisms are discussed.This publication has 12 references indexed in Scilit:
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