Photo-activation of lattice oxygen in vanadium oxide supported on silica
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 77 (9) , 2237-2245
- https://doi.org/10.1039/f19817702237
Abstract
The active oxygen species in the photo-oxidation of carbon monoxide over vanadium oxide supported on silica was confirmed to be lattice oxygen activated by photons. The reaction proceeded by a reduction–oxidation mechanism. The most effective irradiating wavelength was ca. 340 nm. The mechanism of photo-reduction of the catalyst was investigated by a kinetic study.Keywords
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