Highly stereoselective preparation of enantiomerically pure 1,2-diols: synthesis of (+)-exobrevicomin
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 83-84
- https://doi.org/10.1039/c39850000083
Abstract
Reduction of optically pure acyl-lactones (2) by L-Selectride affords monoprotected syn diols with high diastereoselectivity; the reaction was applied to the stereo- and enantio-specific synthesis of (+)-exobrevicomin.Keywords
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