Metathesis of phosphorus-containing olefins catalysed by a cyclometallated aryloxo(chloro)neopentylidene–tungsten complex
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 857-858
- https://doi.org/10.1039/c39950000857
Abstract
A cyclometallated O,O′-diphenyl aryloxy(chloro)neopentylidene–tungsten complex [graphic omitted]r)(OAr)(CHCMe3)Cl(OEt2)1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.Keywords
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