The thermodynamic compensation law
- 14 March 1988
- journal article
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 21 (3) , 383-384
- https://doi.org/10.1088/0022-3727/21/3/001
Abstract
A demonstration of the thermodynamic compensation law is given; this law is shown to be a consequence of experimental approximations. It has been shown that the Meyer-Nelder rule is a consequence of experimental methods that consider a straight-line approximation of the In(X) versus 1/T plot of measurements of a physical quantity X in a limited temperature range. The ability of the Meyer-Neldel rule to give meaningful results is linked to the quality of the measurements and approximations made, but it appears that no genuine physical effect or fundamental relationships or universal quantities underlie its applicability.Keywords
This publication has 7 references indexed in Scilit:
- The diode quality factor of solar cells under illuminationJournal of Physics D: Applied Physics, 1986
- A critical study of the effectiveness of the single and double exponential models for I–V characterization of solar cellsSolid-State Electronics, 1985
- Applicability of the Meyer–Neldel rule to solar cellsApplied Physics Letters, 1984
- Meyer–Neldel rule in solar cellsApplied Physics Letters, 1984
- Charge-Carrier Injection and the Pre-exponential Factor in Semiconducting Organic SubstancesThe Journal of Chemical Physics, 1969
- Pre-exponential Factor in Semiconducting Organic SubstancesThe Journal of Chemical Physics, 1968
- On the Semiconductivity of Crystalline Aromatic SubstancesThe Journal of Chemical Physics, 1955