Chemical significance of aluminium extracted from three horizons of an acid forest soil, using chloride salt solutions

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Abstract
Summary: Aluminium is usually important in exchange reactions in acid soil, but amounts extracted are strongly affected by procedure. We examined the impact of proton release, following salt addition, on Al removal from three horizons (Oe, Oa and A12) of an acid, brown forest soil.The Al was first extracted with either 1 M KC1, 1mNH4C1 or 0.5mCuCl2on the three horizons limed to pH 5.5. For any lime addition, both the pH drop following salt addition and the amounts of extracted Al were greater with CuCl2than with KC1 or NH4C1. For the Oa and A12horizons there was a single inverse linear relation between amount of Al extracted and the pH of final extract, independent of the extracting cation. In the Oe horizon CuCl2extracted constant amounts of Al, whereas the quantity of Al removed by KC1 or NH4C1 increased linearly as pH declined below pH 3.6.Extra Al was mobilized following unbuffered KC1 extraction, a side effect induced by the extracting procedure itself.Al mobilization increased with increasing H+additions. In the Oe horizon, equilibrium was established rapidly (≤ 24 h), and decreasing the pH of the soil‐KCl suspensions to 2.0 resulted in extracted Al amounts equal to or slightly greater than those obtained with CuCl2solutions. Al amounts extracted with acidified KC1 solutions from the A12were close to those obtained using CuCl2solutions at similar pH in the extract. In the samples from the A12layer, increasing the equilibration time resulted in increasing proton consumption and equivalent release of Al ions in the extract.