Stereochemistry of the ring-opening of an activated vinylcyclopropane
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 821-822
- https://doi.org/10.1039/c39720000821
Abstract
Optically active dimethyl 2-vinylcyclopropane-1,1-dicarboxylate reacts with pyrolidine with clean inversion of configuration at C(5); its reaction with enamines appears to involve prior cleavage of the C(3)–C(5) bond.Keywords
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