Polynuclear mixed-metal thiolate complexes with D-penicillamine

Abstract
Diamagnetic cluster-compounds of composition [M8 IM6 II{SC(Me)2CH(NH2)CO2}12Cl]5– with M8 IM6 II= Cu8 INi6 II, Ag8 INi6 II, and Ag8 IPd6 II are structually related to the well characterized Cu8 I Cu6 II compound so that the MI atoms are trigonally co-ordinated by 3 sulphur atoms and the MII atoms are planar 4-co-ordinated by 2 sulphur and 2 nitrogen atoms.

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