A modular approach to ligands for asymmetric π-allyl palladium catalysed additions
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 975-976
- https://doi.org/10.1039/a607200c
Abstract
A route to phosphinodihydrooxazoles is reported, which is used to synthesize ten new ligands whose ability to asymmetrically catalyse the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate is investigated; the best gave a palladium complex which catalyses the addition of dimethyl malonate to 1,3-diphenylprop-2-enyl acetate in 99% yield and 97% ee.Keywords
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