Selective Epoxidation of Polar Substrates by Dimethyldioxirane
- 1 July 1998
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 28 (14) , 2679-2683
- https://doi.org/10.1080/00397919808004837
Abstract
Epoxides of highly inactivated double bounds can be obtained using DMDO, after transformation of deactivating esters into tetrabutylammonium salts. Reactions are quantitative and no further purification is required.Keywords
This publication has 8 references indexed in Scilit:
- Oxidation of Alkyl and Aryl Iodides, Phenylacetaldehyde and Alkenes by Dimethyldioxirane. Reaction Products and Mechanism.Tetrahedron Letters, 1995
- 1,4-dioxene in organic synthesis: Generation and reactivity of epoxydioxenesTetrahedron Letters, 1995
- Efficient desymmetrization of 1,2 and 1,3 diols by dimethyldioxiraneTetrahedron Letters, 1995
- Trapping of free-radicals in the oxidation of ethers, aldehydes and alkanes by dimethyldioxiraneTetrahedron Letters, 1995
- Inhibition of glyceraldehyde-3-phosphate dehydrogenase by phosphorylated epoxides and .alpha.-EnonesBiochemistry, 1994
- Kurzmitteilung / Short Communication A Convenient Preparation of Acetone Solutions of DimethyldioxiraneEuropean Journal of Inorganic Chemistry, 1991
- Dioxirane Epoxidation of α,β‐Unsaturated KetonesEuropean Journal of Inorganic Chemistry, 1991
- Epoxidation and cleavage of .alpha.,.beta.-unsaturated ketones with alkaline hydrogen peroxideThe Journal of Organic Chemistry, 1970