MACROCYCLIZATION OF TRANSITION METAL COMPLEXES OF ALPHA-FURILGLYOXIME AND BENZILGLYOXIME
- 1 July 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 16 (1) , 81-87
- https://doi.org/10.1080/00958978708079809
Abstract
The α-furil- and benzilglyoximates of nickel (II), palladium(II), platinum(II), cobalt(III), rhodium(III) and rhenium(III) have been prepared in a crystalline state and the corresponding macrocycles obtained by reaction with BF3·OE2 utilizing the metal ion as a template. The planar glyoximates yielded macrocycles whereas the macrocyclization of octahedral complexes could not be accomplished. The reactions and the predicted structures have been compared with known structures.Keywords
This publication has 34 references indexed in Scilit:
- A short and nearly symmetrical intramolecular hydrogen bond: x-ray and neutron diffraction analysis of 2,2-(1,3-diaminopropane)bis(2-methyl-3-butanone oximato)nickel(II) chloride hydrateInorganic Chemistry, 1979
- Spectrophotometric determination of nickel and palladium by extraction of their complexes with molten naphthaleneAnalytica Chimica Acta, 1977
- Synergetic extraction and spectrophotometric determination of gold(III)Microchimica Acta, 1977
- Transition metal cluster complexes—I: Trinuclear dimethylglyoximato and acetylacetonedioximato copper(II) complexes. Their infrared and electronic spectra and magnetic propertiesJournal of Inorganic and Nuclear Chemistry, 1974
- The crystal and molecular structure of bis(glyoximato) platinum(II)Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1969
- Some theoretical and practical problems in the use of organic reagents in chemical analysis—IVJournal of Inorganic and Nuclear Chemistry, 1965
- The Radiolysis of Organic Solutions. I. Acetone as a Trap for Hydrogen Atoms1Journal of the American Chemical Society, 1959
- Magnetic Studies of Nickel(II) and Palladium(II) Complexes with Some vic-Dioximes1,2Journal of the American Chemical Society, 1955
- The Magnetic Susceptibility of Some Nickel Complexes in SolutionJournal of the American Chemical Society, 1947
- On the magnetic susceptibilities of some nickel compoundsProceedings of the Physical Society, 1932