Aqueous copper(III) and nickel(III) tetra-aza-macrocyclic complexes
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 646-647
- https://doi.org/10.1039/c39800000646
Abstract
The copper(III) and nickel(III) complexes with the novel tetra-aza-macrocycle 1,4,8,11-tetra-azacyclotetradecane-5,7-dionato(2–)(L2)2–, which contains two deprotonated amido groups, can be generated in aqueous solution by chemical or anodic oxidation of the corresponding CuII and NiII species and the authenticity of the oxidation states is demonstrated by voltammetric and e.s.r. investigations.Keywords
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