Renormalization-group approach to the metal-insulator transitions in (DCNQI is -dicyanoquinonediimine and Cu)
- 15 September 1997
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 56 (12) , 7262-7276
- https://doi.org/10.1103/physrevb.56.7262
Abstract
Metal-insulator transitions and different ground-state phases in the quasi-one-dimensional materials, I and Cu), are studied with a renormalization-group method. We use one-dimensional continuum models with backward scatterings, umklapp processes, and couplings with and phonons (not static lattice distortion). We take a quarter-filled band for and a sixth-filled band coupled with a third-filled band for Depending on electron-electron and electron-phonon coupling strengths, the ground-state phase becomes a Tomonaga-Luttinger liquid or a state with a gap(s). For there appears a spin-gap state with a dominant charge-density-wave correlation, a Mott insulator with a dominant charge-density-wave correlation, or a spin-Peierls state with different magnitudes of spin and charge gaps. Three dimensionality is taken into account by cutting off the logarithmic singularity in either the particle-particle channel or the particle-hole channel. The difference between the ground-state phase of the salt (spin-Peierls state) and that of the salt (antiferromagnetic state) is qualitatively explained by a difference in the cutoff energy in the particle-particle channel. For there appears a Mott insulator with a charge-density wave of period 3 and a Peierls insulator with a charge-ensity wave of period 6. The conditions for the experimentally observed, Mott insulator phase are strong correlation in the sixth-filled band, moderate electron-phonon couplings, and finite electron- phonon coupling. Resistance is calculated as a function of temperature with a memory-function approximation in both cases above. It qualitatively reproduces the differences among the and cases as well as the and cases.
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