Fourier Transform Spectroscopy with Long Absorption Path Length in Solid Hydrogen: Measurement ofΔJ=6andΔJ=8Transitions

Abstract
New features in the infrared spectrum of solid parahydrogen were measured with high resolution (FWHM = 0.006 cm1) and high sensitivity. Two features were assigned as the transitions W00(1) and W10(1) with a change in the angular momentum quantum number of ΔJ=6, and one feature was assigned as the transition Y00(0) with ΔJ=8. An optical multipass system consisting of two spherical mirrors delimits the sample and gives ideally seven passes through the solid. Wave numbers, linewidths, and intensity parameters are reported and the optical performance is described.