SYNTHESIS OF ORGANIC DEUTERIUM COMPOUNDS: X. METHYL-d3 IODIDE AND DEUTERIUM SUBSTITUTION PRODUCTS OF METHYL ACETATE
- 1 January 1954
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 32 (1) , 1-3
- https://doi.org/10.1139/v54-001
Abstract
Methyl-d3 bromide was easily converted by treatment with calcium iodide into methyl-d3 iodide in 94% yield. The latter was reacted on the 50-millimole scale with silver acetate or silver acetate-d3 to yield methyl-d3 acetate or methyl-d3 acetate-d3. Methyl iodide and silver acetate-d3 gave methyl acetate-d3.Keywords
This publication has 1 reference indexed in Scilit:
- XC.—The vapour pressures, molecular volumes, and critical constants of ten of the lower estersJournal of the Chemical Society, Transactions, 1893