The Crystal Structure of Sodium Nickel Arsenate, NaNiAsO4

Abstract
The unit cell of NaNiAsO4 is rhombohedral, space group R 3, with a = 4.955(5) Å, c = 26.47(3) Å and Z - 6. The crystal structure com­prises three-layer units consisting of one “octahe­dral" layer, built up from Ni06-octahedra, and two “tetrahedral" layers, built up from AsO4-tetrahe- dra. Sodium ions are situated between these layers, having a distorted (4+3) coordination.

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