Isolation and structural determination of two derivatives of the elusive carbamic acid

Abstract
The dibenzyl-substituted carbamic acid (PhCH2)2NC(O)OH (1), its deprotonation product [(PhCH2)2NH2]- [(PhCH2)2NCO2] (2) and CoCl(NO)2[PhP(OCH2CH2)2NC(O)OH ]·2MeCOMe(3·2MeCOMe) are reported, the diffractometric study showing the carbamic acids 1 and 3 to be paired through hydrogen bonds.

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