A new method for solving the coupled equations in the adiabatic representation
- 1 October 1978
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 69 (7) , 3414-3421
- https://doi.org/10.1063/1.436948
Abstract
A new method for solving the coupled equations in the adiabatic representation which arise in quantum mechanical treatment of atomic and molecular collisions is developed. The solutions of the uncoupled adiabatic equations, obtained from the coupled equations in the adiabatic representation by neglecting the coupling terms, are used to derive a set of new exact equations for the purely inelastic effects of the collision. The solutions of the new equations are practically nonoscillatory and can be solved numerically with little computational effort.Keywords
This publication has 40 references indexed in Scilit:
- Quantum calculations and classical interpretation of a model curve-crossing problemPhysical Review A, 1975
- Curve Crossing for Low-Energy Elastic Scattering ofby NePhysical Review A, 1973
- Theory of Inelastic Collisions: Uniform Asymptotic (WKB) Solutions and Semiclassical Scattering Matrix Elements for Multichannel ProblemsThe Journal of Chemical Physics, 1972
- Theory of Inelastic Collisions: Uniform Asymptotic (WKB) Solutions and Semiclassical S-Matrix Elements for Two-Channel ProblemsThe Journal of Chemical Physics, 1971
- Quantum-Mechanical Calculation of Cross Sections for Inelastic Atom-Atom Collisions. II. Model Calculation under Various Coupling ConditionsPhysical Review A, 1971
- Collision of an Atom and a Diatomic. The Adiabatic ApproximationThe Journal of Chemical Physics, 1971
- Studies of the Potential-Curve Crossing Problem. I. Analysis of Stueckelberg's MethodPhysical Review A, 1971
- Uniform asymptotic expansions of solutions of linear second-order differential equations for large values of a parameterPhilosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1958
- On the Connection Formulas and the Solutions of the Wave EquationPhysical Review B, 1937
- Zur Quantentheorie der MolekelnAnnalen der Physik, 1927