THE HIGHLY STEREOSELECTIVE SYNTHESIS OF CIS-VINYLOXIRANES
- 5 February 1982
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 11 (2) , 237-240
- https://doi.org/10.1246/cl.1982.237
Abstract
In the presence of triethylaluminum, oxyallyl anions derived from 2-allyloxybenzimidazoles react with aldehydes in highly regio-and stereoselective manner to afford α-adducts in good yields. The adducts are stereospecifically converted to cis-vinyloxiranes in good yields.Keywords
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