Reduced Nitrosyl Polyoxomolybdates with the Hitherto Unknown Decamolybdate Y Structure: Preparation and Crystal and Electronic Structures of the Two-Electron Reduced [Mo10O25(OMe)6(NO)]-and the Four-Electron Reduced [Mo10O24(OMe)7(NO)]2-
- 1 April 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 119 (15) , 3523-3535
- https://doi.org/10.1021/ja9635140
Abstract
No abstract availableThis publication has 76 references indexed in Scilit:
- Evaluations of a General NMR Method, Based on Properties of Heteropoly Blues, for Determining Rates of Electron Transfer through Various Bridges. New Mixed-Mixed Valence ComplexesJournal of the American Chemical Society, 1995
- Reduced polyoxomolybdates with the Keggin and Dawson structures: preparation and crystal structures of two-electron reduced [K(18-crown-6)]2[N(PPh3)2]2[HPMo12O40]·8MeCN·18-crown-6 and four-electron reduced [NBun4]5[H3S2Mo18O62]·4MeCn (18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane)J. Chem. Soc., Dalton Trans., 1995
- The "Alternate" Keggin Ion: A Theoretical Study of the Stability Factors for the .beta.-Keggin Ion in Comparison with the Corresponding .alpha.-Keggin IonChemistry of Materials, 1994
- A green heteropoly blue: isolation of a stable, odd oxidation level in a Dawson molybdate anion, [S2Mo18O62]5-Inorganic Chemistry, 1993
- 17O n.m.r. of paramagnetic heteropoly blues. Discrimination between electron delocalisation pathways and between intermolecular electron transfer ratesJournal of the Chemical Society, Chemical Communications, 1989
- Ring currents in wholly inorganic heteropoly blue complexes. Evaluation by a modification of Evans' susceptibility methodJournal of the American Chemical Society, 1988
- Direct determination by tungsten-183 NMR of the locations of added electrons in ESR-silent heteropoly blues. Chemical shifts and relaxation times in polysite mixed-valence transition metal speciesJournal of the American Chemical Society, 1986
- Structure of a heteropoly blue. The four-electron reduced .beta.-12-molybdophosphate anionJournal of the American Chemical Society, 1985
- Electron delocalization in mixed-valence tungsten polyanionsJournal of the American Chemical Society, 1983
- Reduction de l'ion metatungstate: Stades eleves de reduction de H2W12O406−, derives de l'ion HW12O407− et discussion generaleJournal of Inorganic and Nuclear Chemistry, 1976