Control of the reactivity of cyclopalladated complexes for the synthesis of heterocyclic compounds
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 565-567
- https://doi.org/10.1039/c39870000565
Abstract
Reactions between iodide or cationic derivatives of cyclopalladated complexes and alkynes lead to the synthesis of heterocyclic compounds through insertion of one or two alkynes into the Pd–C bonds, the new N–C bonds being formed via reductive elimination of palladium(0).Keywords
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