Determination of Magnetic and Nuclear Quadrupole Interactions in La@C82from EPR Linewidth Data
- 1 July 1996
- journal article
- research article
- Published by Taylor & Francis in Fullerene Science and Technology
- Vol. 4 (4) , 655-675
- https://doi.org/10.1080/10641229608003009
Abstract
From the analysis of the temperature dependence of the EPR line width, an estimate of the anisotropic parts of the dipolar and quadrupolar hyperfine couplings of lanthanum was derived. Furthermore, the rotational correlation time of the nearly spherical molecule was found to deviate considerably from that of the solvent molecules.Keywords
This publication has 11 references indexed in Scilit:
- 2D EPR investigation of endohedral La@C82 in solutionChemical Physics Letters, 1995
- Fourier transform EPR studies of metallofullerene (La@C82) in CS2 solutionChemical Physics Letters, 1995
- Spin Dynamics of C60 TripletsThe Journal of Physical Chemistry, 1994
- ESR study of the electronic structures of metallofullerenes: a comparison between lanthanum fullerene (La@C82) and scandium fullerene (Sc@C82)The Journal of Physical Chemistry, 1993
- Theoretical aspects of chemically induced magnetic polarizationResearch on Chemical Intermediates, 1991
- Rotational friction coefficients for spheroids with the slipping boundary conditionThe Journal of Chemical Physics, 1974
- Spin-rotational relaxation in solution E.S.R.Molecular Physics, 1967
- ESR Linewidths in Solution. I. Experiments on Anisotropic and Spin—Rotational EffectsThe Journal of Chemical Physics, 1966
- Theory of Linewidths in Electron Spin Resonance SpectraThe Journal of Chemical Physics, 1963
- Theory of the Effects of Exchange on the Nuclear Fine Structure in the Paramagnetic Resonance Spectra of LiquidsThe Journal of Chemical Physics, 1957