Silylene complexes from a stable silylene and metal carbonyls: synthesis and structure of [Ni{(ButN–CHCH–NBut)Si}2(CO)2], a donor-free bis-silylene complex
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 33-34
- https://doi.org/10.1039/c39940000033
Abstract
[Ni(LSi)2(CO)2]3; the first silylene complex of nickel, has been obtained from the stable silylene 1,3-di-tert-2,3-dihydro-1H-1,3,2-diazasilol-2-ylidene (LSi)1 and tetracarbonylnickel; complex 3 was characterized by single crystal X-ray diffraction and NMR spectroscopy (1H, 13C, 29Si).Keywords
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