Mild and Efficient Conversion of Allylic Alcohols to Xanthates
- 1 March 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (5) , 625-632
- https://doi.org/10.1080/00397919008052302
Abstract
The reaction of allylic alcohols (4–7) with sodium hydroxide, carbon disulfide and methyl iodide followed by heteroclaisen rearrangement over neutral alumina furnished (18–21) in 70–90% isolated yield.Keywords
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