Stereoselective Synthesis of Angularly Methylated Trans Fused Hydrindanone by Conjugate Reduction
- 1 May 1986
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 16 (6) , 639-643
- https://doi.org/10.1080/00397918608057733
Abstract
The reducing reagent consisting of methylcopper, diiso-butylaluminum hydride and hexamethylphosphoric triamide causes the stereoselective trans conjugate reduction of the hydrindenone 1 to produce predominantly the angularly methylated trans fused hydrindanone 3.Keywords
This publication has 3 references indexed in Scilit:
- Methods for stereospecific synthesis ofTetrahedron Letters, 1984
- Stereochemical control of the internal Michael reaction. A new construction of trans-hydrindan systemsJournal of the American Chemical Society, 1982
- Photochemical rearrangements of bicyclic 6/5-fused cross-conjugated cyclohexadienones and related compoundsThe Journal of Organic Chemistry, 1972