Preparation and characterisation of a penta-ammineruthenium(III) derivative of plastocyanin and the kinetics of long distance electron transfer
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 65-66
- https://doi.org/10.1039/c39870000065
Abstract
Attachment of RuIII(NH3)5 to the His59 of Anabaena variabilis plastocyanin, reduction of the RuIII to RuII by pulse radiolysis techniques, and determination of the rate constant (0.3 s–1) for intramolecular electron transfer RuII→ CuII(11.9 Å) is described.Keywords
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