Chlorotrimethylsilane-Acetonitrile System as a New Promoter for Carbonyl Allylation by Diallyldibutyltin
- 1 March 1995
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 24 (3) , 167-168
- https://doi.org/10.1246/cl.1995.167
Abstract
Chlorotrimethylsilane combined with acetonitrile has characteristically promoted allylation of carbonyl compounds by diallyldibutyltin to produce a variety of homoallyl silyl ether in good yields, while the addition of HMPA or LiCl disturbed the allylation.Keywords
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