Amplitude of the Charge-Density Waves in1T- and2H-TaSe2

Mössbauer ${}_{}{}^{181}{}_{}{}^{}\mathrm{Ta}$ spectra of $1T$-Ta${\mathrm{Se}}_2$ at 300 K show only two of three Ta sites predicted by 6:6:1 charge-density-wave models. They have equal amplitude and are separated by a shift the authors calibrate as 0.34(0.17) electrons. The unseen site is experimentally excluded from the region between ${\mathrm{Ta}}^{4+}$ and ${\mathrm{Ta}}^{5+}$. Site linewidths limit possible secondary splittings by interlayer effects to 0.018 of the primary splitting. The $2H$-Ta${\mathrm{Se}}_2$ data at 52 K are consistent with an orthorhombic charge-density wave with three equal Ta sites at -0.049(0.020), +0.033(0.016), and +0.023(0.011) electrons relative to ${\mathrm{Ta}}^{4+}$.