Synthesis of organouranium(V) compounds by oxidation of neutral tetravalent precursors. Crystal structures of [U(η-C5Me5)(NMe2)3(OC4H8)][BPh4] and [U(η-C5Me5)2(NEt2)2][BPh4], the first cationic uranium(V) complexes
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 5,p. 543-544
- https://doi.org/10.1039/c39950000543
Abstract
The cationic organouranium(V) compounds [U(η-C5Me5)(NMe2)3(thf)][BPh4]1, [U(η-C5Me5)2(Net2)2][BPh4]2 and [U(η-C8H8)(NEt2)2(thf)][BPh4]3, were synthesized by oxidation of the corresponding neutral UIV precursors using AgBPh4; the neutral complex [U(η-C8H8)(η-C5H5)(NEt2)2]4 was isolated from the reaction of [U(η-C8H8)(NEt2)2] with Tl(η-C5H5).Keywords
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