Oxidative addition reactions of aldehydes and related molecules with tetrakis(triphenylphosphine)platinum(0)
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 4,p. 198
- https://doi.org/10.1039/c29700000198
Abstract
Aldehydes react with Pt(PPh3)4 to give platinum-diacyl complexes of the type, Pt(COR)2(PPh3)2; the β-dicarbonyl compounds, acetylacetone and diethyl malonate react with Pt(PPh3)4 to give complexes in which the enol form is complexed to platinum.Keywords
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