Novel routes to new organoimido (organonitrene) complexes of molybdenum, rhenium, and osmium
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 549
- https://doi.org/10.1039/c39720000549
Abstract
The reaction of phosphinimines of the type RN = PPh3(R = PhCO or Ph) with rhenium and osmium oxo-complexes provides a new route to arylimido-complexes and to the previously unknown rhenium aroylimido- and osmium arylimido-complexes; a series of novel molybdenum arylimido-derivatives has been obtained from a molybdenum oxo-complex and 1,2-disubstituted hydrazines.Keywords
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