Steric and electronic effects on the chemistry of molybdenum octahedrally co-ordinated by six nitrogen atoms. The molecular structure of [Mo{HB(3,5-Me2C3N2H)3}(NO)(pyrollide)2]
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 690-692
- https://doi.org/10.1039/c39840000690
Abstract
[Mo{HB(3,5-Me2C3N2H)3}(No)I2] reacts with the nitrogen heterocycles Z to give [Mo{HB(3,5-Me2C3N2H)3}(NO)Z2]+, where Z = pyridine, imidazole, N-methylimidazole, or pyrazole, with monosidium organoamides to give [Mo{HB(3,5-Me2C3N2H)3}(NO)Y2] where Y = NHEt–, NHPh–, p-NHC6H4Me–, or pyrollide, and with moist tetrahydrofuran to give [Mo{HB(3,5-Me2C3N2H)3}(NO)I{O[CH2]4I}]; the molecular structure of [Mo{HB(3, 5-Me2C3N2H)3}(NO)-(pyrollide)2] has been determined.Keywords
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