•NO2-Mediatedmeso-Hydroxylation of Iron(III) Porphyrin
- 2 March 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 48 (5) , 1790-1792
- https://doi.org/10.1021/ic800864w
Abstract
(*)NO(2) generated from (*)NO and air add to iron(III) porphyrin upon nitration, which isomerized spontaneously to hydrolysis, yielding a meso-hydroxylated cation that seized by the end oxidation product, a nitrate ion, through extensive hydrogen bonding.Keywords
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