The pulse radiolysis of 1-propanol at 147 to 300 K
- 15 February 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (4) , 531-536
- https://doi.org/10.1139/v76-074
Abstract
Using ∼20 ns electron pulses the spectra and kinetics of the electron and an absorption in the uv in 1-propanol have been determined at temperatures from 147 to 300 K. The uv absorption is attributed to the hydroxy propyl radical, CH3CH2ĊHOH; it is formed within ∼20 ns over this temperature range and disappears by second order kinetics. The results for the formation of the solvated electron are in agreement with those of Baxendale and Wardman. The temperature dependence of both the radical–radical reaction and the reaction of the solvated electron with N2O is very nearly the same as that of T/η.Keywords
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