Instrumentation and data acquisition for i n s i t u electrochemistry at the Daresbury SRS

Abstract
X‐ray diffraction and absorption spectroscopy provide complementary structural tools for the in situ characterization of electrode surfaces. To optimize surface sensitivity, techniques such as glancing angle scattering geometries and spectrum differencing can be employed while the application of synchrotron radiation allows the real‐time collection of data. This paper outlines recent developments in in situ electrochemistry on the Daresbury SRS and describes an electrochemical cell for in situ x‐ray studies, associated glancing angle instrumentation, together with computer hardware and software optimized for data acquisition using potential modulation techniques. Important fundamental and industrial applications are highlighted.

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