A CONVENIENT METHOD FOR THE PREPARATION OF VINYL SULFIDES FROM CARBONYL COMPOUNDS BY USING TiCl4

Abstract
Various ketones, such as deoxybenzoin, propiophenone, phenylacetone, benzylacetone, cyclohexanone and 2-methylcyclohexanone, and aldehyde such as 3-phenylpropionaldehyde were smoothly converted to the corresponding vinyl sulfides in good yields by the treatments with thiols in the presence of TiCl4.

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