Formation of a specific co-ordination cavity for a chiral amino acid by template synthesis of a polymer Schiff base cobalt(III) complex
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 415-417
- https://doi.org/10.1039/c39850000415
Abstract
A template polymer complex, which incorporates N-benzyl-D-valine with almost 100% stereospecificity, was synthesised by copolymerization of Δ-β2-[CO{(R,R)-N,N′-bis[4-(p-vinylbenzyloxy)salicylidene]-1,2-diaminocyclohexane}(N-benzyl-D-valine)](3), styrene, and divinylbenzene, followed by dissociation of the co-ordinated amino acid.Keywords
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