Kinetics of Radical Polymerization. XLI. Kinetic Investigation of the Radical Polymerization of Methyl Methacrylate in Benzene and Bromobenzene
- 1 February 1985
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 22 (2) , 203-212
- https://doi.org/10.1080/00222338508063306
Abstract
The present paper deals with the radical polymerization kinetics of the systems MU-AIBN-Bz-50°C and MMA-AIBN-BrBz-50°C. The rate of initiation and the k2/√k4 value were determined in a broad range of monomer concentrations. The initiation rate constant was found to be independent of the concentration of solvent and monomer. In the system MMA-Bz the k2/√K4 value does not change with dilution, while in the system MMA-BrBz it depends on the viscosity of the initial monomer-solvent mixture.Keywords
This publication has 7 references indexed in Scilit:
- The influence of solute-solvent interactions on the kinetics and stereospecificity of polymerization-the relevance of aromatic solvent shifts observed on the nmr spectrum of methyl methacrylateEuropean Polymer Journal, 1973
- Der Einfluß des Lösungsmittels auf die Teilreaktionen bei der radikalischen Polymerisation des MethylmethacrylatesBerichte der Bunsengesellschaft für physikalische Chemie, 1969
- An improved kinetics for radical polymerization on the basis that the viscosity of the solvent plays an important roleJournal of Polymer Science Part B: Polymer Letters, 1968
- Über den Lösungsmitteleinfluß bei der RadikalpolymerisationZeitschrift für Physikalische Chemie, 1966
- ber Verdazyle, eine neue Klasse cyclischer N-haltiger RadikaleMonatshefte für Chemie / Chemical Monthly, 1964
- Diffusion-controlled termination during the initial stages of free radical polymerization of methyl methacrylateTransactions of the Faraday Society, 1961
- Kinetics of the Polymerization of Methyl Methacrylate with Aliphatic Azobisnitriles as Initiators1Journal of the American Chemical Society, 1952