Thermodynamic considerations in co-ordination. Part XII. Potentiometric and calorimetric investigations of the complexing between the phenylalanate anion and iron(II), iron(III), cobalt(II), nickel(II), and copper(II)
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 18,p. 1988-1990
- https://doi.org/10.1039/dt9720001988
Abstract
Formation constants for AB and A2B (A = phenylalanate, B = FeII and FeIII, CoII, NiII, and CuII) and for FeIIA3, FeIII 2A2(OH)2, and CuII 2A2(OH)2 are reported for I= 3·00M-(Na+)ClO4 – at 25 °C and corresponding enthalpies and entropies of formation were determined calorimetrically for the Co, Ni, and Cu complexes listed above.Keywords
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