Na+-Mediated aggregation of imino-carboxylate transition metal complexesElectronic supplementary information (ESI) available: further crystallographic details. See http://www.rsc.org/suppdata/dt/b1/b107873a/
- 11 October 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 21,p. 3137-3139
- https://doi.org/10.1039/b107873a
Abstract
The imino-carboxylate complexes [M(L)]− (M = Mn, Ni) form the polymers {[Mn(L)]2Na4Cl2·13H2O}∞ and {[Ni(L)]2Na4(BF4)2}∞ in the presence of Na+; the degree of aggregation can be controlled by variation of the counter-anion and the amount of Na+ present, the Na+ ions forming sandwiched layers between aggregates of [M(L)]−.Keywords
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