Indirect spin coupling constants in fluorine compounds of five- and six-co-ordinate phosphorus

Abstract
Magnitudes and signs of indirect spin coupling constants relative to 1J(CH) > 0 were investigated by heteronuclear INDOR-technique in the series MenPF5–n(n= 1,2,3) and in [MePF5] showing that 1J(PFa) < 0, 1J(PFe) < 0, and 1J(PC) > 0.

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