Synthesis of erivanin and 1-epierivanin from 1-(α)-santonin
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 9,p. 2633-2637
- https://doi.org/10.1039/p19880002633
Abstract
Synthesis of erivanin (2) along with its 1-epimer (17) is reported starting from 1-(α)-santonin, the crucial step in the synthesis being the successful application of Mitsunobu epimerisation procedure on a eudesmanic alcohol (15a) in bringing about inversion of configuration at C-1.Keywords
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