The aromatic nitrene–carbene interconversion
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 23,p. 1386-1387
- https://doi.org/10.1039/c29690001386
Abstract
Gas-phase pyrolysis of 2,6-dimethylphenyl azide (IIIc) gives 2-vinyl-6-methylpyridine (Vc) in agreement with nitrene–carbene interconversion via 2-azatropylidene (II) or valence isomers thereof.Keywords
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