REARRANGEMENT OF TETRAKIS(HYDROXYMETHYL)-PHOSPHONIUM CHLORIDE UPON ACID HYDROLYSIS
- 1 December 1978
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 5 (2) , 197-199
- https://doi.org/10.1080/03086647808069886
Abstract
Tetrakis(hydroxymethyl)phosphonium chloride (2) rearranges to bis(hydroxymethyl)methylphosphine oxide (3) upon acid hydrolysis. The extent of rearrangement increases with acid strength, but the product is apt to undergo further reaction, losing one or both of its hydroxyl functions.Keywords
This publication has 10 references indexed in Scilit:
- Synthesis and properties of carbamate derivatives of tetrakis(hydroxymethyl)phosphonium chlorideThe Journal of Organic Chemistry, 1977
- The Iodometric Determination of P(III) in Flame Retardants for CottonTextile Research Journal, 1977
- The Iodometric Determination of P(III) in Flame Retardants for CottonTextile Research Journal, 1973
- Effect of high speed pumps on the determination of gases in metals by the vacuum fusion methodAnalytical Chemistry, 1973
- A Study of Dissociation Constant of p-Toluenesulfonic Acid by Nuclear Magnetic ResonanceJournal of Nuclear Science and Technology, 1971
- Synthesis of some halomethylphosphine oxidesJournal of Chemical & Engineering Data, 1967
- Phosphonium Compounds. III. Mechanism of Hydroxide Cleavage of Tetrakis(hydroxymethyl)phosphonium ChlorideJournal of the American Chemical Society, 1963
- Hydroxymethyl‐phosphine, Hydroxymethyl‐phosphoniumsalze und Chlormethyl‐phosphoniumsalzeEuropean Journal of Organic Chemistry, 1962
- 548. The rearrangement of l-hydroxyalkylphosphines to alkylphosphine oxidesJournal of the Chemical Society, 1961
- Acid-Base Equilibria in Glacial Acetic Acid. I. Spectrophotometric Determination of Acid and Base Strengths and of Some Dissociation Constants1Journal of the American Chemical Society, 1956