Antimony-121 Mössbauer spectroscopy of some chloro-complexes of antimony
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1855-1857
- https://doi.org/10.1039/j19710001855
Abstract
The 121Sb Mössbauer spectra of a number of chloroantimony salts have been examined. The presence of both SbIII and SbV in Rb2SbCl6 is confirmed. Extremely large, negative isomer shifts are obtained for [SbIIICl6]3– species and are interpreted in terms of a stereochemically inactive Ione-pair of electrons.Keywords
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