STUDIES IN VILSMEIER-HAAK REACTION. PART II. APPLICATION TO SOME 1-PHENYL-3-METHYL-4-AZOSULPHONAMIDO-5-PYRAZOLONE DYES
- 1 July 1989
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 44 (1) , 135-141
- https://doi.org/10.1080/10426508908043716
Abstract
The Vilsmeier-Haak reaction on 3-methylpyrazolone azosulphonamide derivatives (1,2) has been shown to lead to chlorination of the 5-oxopyrazolone system in addition to diformylation of the 3-methyl group to give the corresponding aminoacroleins (3,4), respectively. On treatment with some reagents 3, 4 give compounds 9–20 with different heterocyclic systems in the 3-position.Keywords
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